Raw material processing and material refinement: the basis for sustainable battery production
Materials such as lithium and nickel are still components of current battery cells. Their chemical and physical properties make high energy densities and long lifetimes possible, but their extraction and processing pose complex issues.
However, battery technologies are developing rapidly with the industry aiming at minimizing the use of rare and expensive raw materials. The Chinese battery manufacturer CATL presented a sodium-ion battery in 2021 that completely dispenses with lithium and cobalt. In April 2024, CATL launched a cobalt-free lithium iron phosphate (LFP) battery that can power an automobile for over 1,000 kilometers on a single charge. In just ten minutes it can charge enough energy for 600 kilometers, which corresponds to a charging speed of one kilometer per second.
Toyota plans to use solid-state batteries in hybrid vehicles starting in 2025. Nissan has put a prototype production plant for laminated solid-state batteries into operation in Japan. Panasonic has presented a solid-state battery for drones. VW and Mercedes, Ford and BMW are about to introduce solid-state batteries or have entered into strategic partnerships.
A key starting point for new battery technologies is material refinement at the nano level; here, raw materials are specifically processed and functionalized to maximize their performance in batteries. This is what the Surface Technology and Ablation Department at the Fraunhofer Institute for Laser Technology is examining. With modern laser technologies it can precisely intervene in the material structure and to minimize the consumption of resources at the same time.
Another example of the successful use of laser technologies can be found in the collaboration between Fraunhofer ILT, the Chair of Laser Technology LLT at RWTH Aachen University, TRUMPF and the German Electron Synchrotron DESY. By using X-rays from a particle accelerator, the engineers have been able to gain deeper insights into laser welding processes. They showed that using lasers with a green wavelength improves material utilization and reduces waste. Their findings not only offer technological advantages, but also contribute to more sustainable production.
"These projects show that innovative laser technology can not only overcome the challenges of raw material processing, but also enable sustainable and competitive battery production in Europe," explains Dr. Alexander Olowinsky, head of Joining and Cutting at Fraunhofer ILT.
Electrode production: innovations for sustainable production
The current conductor foils (copper or aluminum) have to be coated with the electrode materials for the anode and cathode, and subsequently dried – crucial steps that influence both the energy density and the cycle life of the batteries. Conventional drying processes based on convection ovens, however, consume a considerable amount of energy and require a large amount of space, which limits the sustainability and efficiency of battery production.
The IDEEL project (Implementation of Laser Drying Processes for Economical & Ecological Lithium- Ion Battery Production), funded by the German Federal Ministry of Education and Research, shows how laser drying solves these challenges: In the project, anodes and cathodes were dried in a roll-to-roll process for the first time using a high-power diode laser. This method significantly reduces energy consumption, doubles the drying speed and halves the space required.
"Laser drying not only enables more efficient process control, but also helps to significantly improve the carbon footprint of battery production," explains Dr. Samuel Moritz Fink, group manager for the Thin-Film Processing group at Fraunhofer ILT. Together with the project partners, Fink and his team have developed a laser drying module with adapted optics and process monitoring to ensure uniform drying. This approach also offers flexibility: Existing convection ovens can be retrofitted with the laser technology, making it easier to implement the innovative process in existing production lines.
In another research project, Fraunhofer ILT is using specially developed multi-beam optics. This optical assembly splits the laser beam into several partial beams that simultaneously process a 250 millimeter wide ribbon of a lithium-ion battery anode. This high-precision structuring increases the energy density and improves fast-charging capability.
Electrode production also benefits from the integration of artificial intelligence into the manufacturing process. Researchers at Fraunhofer ILT are currently investigating how AI-supported systems can be used to optimize process parameters. Such systems may not only further increase quality and productivity, but also lay the foundation for autonomous production.
Cell assembly: precision and efficiency through innovative technologies
In addition to drying the electrodes, the precise joining of the electrode materials also plays a central role in the performance and reliability of batteries. Laser microwelding has established itself as a key technology here since it can join materials such as copper and aluminum, essential for battery electrodes, without contacting them and at high precision. Thanks to the low thermal load, the sensitive cell chemistry remains intact, while the electrical conductivity is optimized through reduced contact resistance. Laser microwelding provides a combination of flexibility and efficiency that traditional welding processes cannot match.
The requirements for laser microwelding vary depending on the cell format, as each cell type presents specific challenges when it comes to contacting. Cylindrical cells require a precise welding depth to ensure electrical conductivity, on the one hand, and to prevent damage due to overheating, on the other. Contacting the negative pole poses particular challenges, as excessive heat can damage the sensitive polymer seal, which could result in electrolyte leakage. In the case of pouch cells, which are characterized by their flexible design and high energy density, welding through the sensitive film coating must be avoided.
One promising development in cell assembly can be found the XProLas project, which TRUMPF is carrying out in collaboration with Fraunhofer ILT and other partners. They aim to develop compact, laser-driven X-ray sources that enable on-site quality testing directly at the manufacturer's premises, instead of using large particle accelerators as was previously the case. This new technology makes it possible to analyze battery cells in real time, allowing both the charging and discharging processes and the material quality to be monitored precisely. This method opens up new possibilities, especially when the cathode material needs to be examined; the material determines battery performance and durability. "By using brilliant X-ray sources, we can detect impurities and material defects at an early stage and, thus, significantly shorten development times," explains Dipl.-Ing. Hans-Dieter Hoffmann, head of the Lasers and Optical Systems Department at Fraunhofer ILT.
Here, too, the integration of artificial intelligence opens up additional potential: AI-supported systems can monitor and adjust process parameters in real time. With it deviations can be detected and corrected at an early stage, creating the basis for autonomous production. The vision of "first-time-right" production, in which all components are assembled without errors in the first run, is, therefore, within reach.